Contents
Russian Journal of Physical Chemistry


Vol. 74, No. 2, 2000

Simultaneous English language translation of the journal is available from MAIK “Nauka / Interperiodica” (Russia). Russian
Journal of Physical Chemistry
ISSN 0036-0244.


Chemical Thermodynamics and Thermochemistry

Thermochemistry of Solution of Natural Porphyrins in Benzene–Electron Donor Mixed Solvents

O. M. Chernova and M. B. Berezin p. 141  abstract

The Heat Capacity of Solid Gallium Arsenide

V. M. Glazov, A. S. Malkova, L. M. Pavlova, and A. S. Pashinkin p. 145  abstract

The Caloric Properties of Copper: Thermal Vacancies

V. Ya. Chekhovskoi and V. D. Tarasov p. 150  abstract

The Standard Enthalpies of Formation of the HgBa2CuO4+ ( = 0.02, 0.08, and 0.11)
Superconducting Phase and Ba2CuO3.05

A. S. Monaenkova, A. A. Popova, L. A. Tiflova, N. V. Zaitseva,
T. O. Pleshakova, V. A. Aleshin, and D. A. Mikhailova
p. 155  abstract

The Energy Characteristics of Complex Oxides with La2CuO4 and Ba2CuO3 Structures:
The Enthalpy of Changes in the Coordination of Trivalent Copper Ions
in an Oxygen Environment

L. A. Reznitskii p. 159  abstract

The Critical Properties of a Lennard-Jones Fluid in Narrow Slit-like Pores

A. M. Vishnyakov, E. M. Piotrovskaya, E. N. Brodskaya,
E. V. Votyakov, and Yu. K. Tovbin
p. 162  abstract

The Influence of Pressure on the Thermodynamic Properties
of the YBa2Cu3O6+z Solid Solution

V. V. Kuz’menko, E. B. Rudnyi, and G. F. Voronin p. 168  abstract


Chemical Kinetics and Catalysis

Mathematical Modeling of Carbon Deposition during Partial Oxidation
of Ethylene Glycol to Glyoxal

L. A. Arkatova, L. N. Kurina, S. M. Samokhvalova, and L. P. Shilyaeva p. 173  abstract

The Structure and Catalytic Activity of Copper(II) Complexes
with Dimethylformamide Immobilized on the Surface of Silica

A. I. Kokorin, E. N. Golubeva, N. A. Zubareva, V. I. Pergushov,
S. N. Lanin, and A. A. Kuznetsova
p. 178  abstract


Physical Chemistry of Solutions

The Acidic Properties of Cations and the Solubility of Metal Oxides
in the SrCl2–KCl–NaCl Eutectic Melt at 700°C

V. L. Cherginets and T. P. Rebrova p. 184  abstract

Viscosity of n-Decane–n-Alkanol Binary Mixtures: Application
of Free Volume Theory Combined with Molecular Association

E. D. Totchasov, M. Yu. Nikiforov, I. A. Luk’yanchikova, and G. A. Al’per p. 187  abstract

Differential Heat Effects, Kinetics, and Mechanisms for the Drying
and Water Vapor Wetting of the Acrylamide–Water System

V. E. Ostrovskii, B. V. Tsurkova, E. A. Kadyshevich, and B. V. Gostev p. 191  abstract

Relation between the Interionic Interaction Potential of the Modernized Bjerrum Theory
and the Solvation Energies of Cations and Anions

A. I. Mishustin p. 202  abstract


Structure of Matter and Quantum Chemistry

New Low-Temperature Phase of YBa2Cu3O6+ ( = 0.1–1.7)

A. V. Fetisov and B. V. Slobodin p. 206  abstract

IR Absorption Spectra of Gaseous o-Cresotinic, Isophthalic, and Terephthalic Acids

Yu. Ya. Kharitonov and I. I. Oleinik p. 211  abstract


Physical Chemistry of Surface Phenomena

Molecular Sorption of Aliphatic -Amino Acids by Carboxyl Ionites
from Binary Aqueous-Ethanolic Solutions

F. N. Kaputskii, T. L. Yurkshtovich, G. L. Starobinets,
P. M. Bychkovskii, and T. I. Borshchenskaya
p. 215  abstract

Various Approaches to Calculating the Activity Coefficients and Ionic Exchange Constants
for the Tryptophan–Water–AV-17-2P High Basicity Anionite (OH-Form) System

A. V. Kaznacheev, O. N. Khokhlova, V. F. Selemenev, and V. Yu. Khokhlov p. 221  abstract

A Statistical Analysis of the Characteristics of Sorption of Aromatic
and Heterocyclic Amino Acids by High-Basicity Anionites

I. V. Aristov, V. Yu. Khokhlov, O. N. Khokhlova, O. V. Bobreshova, and V. F. Selemenev p. 225  abstract


Physical Chemistry of Separation Processes. Chromatography

Specific Features of the Behavior of Disklike Liquid-Crystal Stationary Phases in Gas Chromatography

O. B. Akopova, L. S. Shabyshev, Z. P. Vetrova, and N. T. Karabanov p. 230  abstract

A Gas-Chromatographic Study of the Thermodynamic Characteristics
of the Interaction of Sorbates with Combined Liquid Phases Prepared
from Polyethylene Glycol and Metal Acetylacetonates

Yu. G. Slizhov, M. A. Gavrilenko, T. N. Matveeva, and N. V. Pozhidaeva p. 234  abstract

Separation of Fullerenes C60 and C70 on Silica Gels Grafted
with Immobilized Tetraphenylporphyrin Derivatives

L. L. Gumanov, B. L. Korsunskii, and V. Ya. Davydov p. 237  abstract

Theoretical Work of Preparative Separation

V. P. Chizhkov and A. A. Ignat’ev p. 241  abstract


Colloid Chemistry and Electrochemistry

Description of Ion-Exchange Dynamics at an Isothermal Supersaturation
in the Presence of Colloid Particles on the Surface of Sorbent Granules

N. A. Tikhonov, R. Kh. Khamizov, and V. V. Kirshin p. 246  abstract


Other Problems of Physical Chemistry

Modeling of the Internal Friction in Liquids on the Basis of Rational Parameters

V. N. Afanas’ev and E. S. Panenko p. 253  abstract

Mobility of Lithium Ions in the Crystal Structure of Lithium Gadolinium Molybdate LiGd(MoO4)2

N. U. Venskovskii, A. V. Mosunov, B. Sh. Galyamov, and S. Yu. Stefanovich p. 260  abstract


Short Communications

Heat Capacity, Enthalpy, Entropy, and Gibbs Free Energy
of Europium Hexaboride in the Range 4.5–300 K

N. N. Sirota and V. V. Novikov p. 264  abstract

Thermochemical Electronegativities of Metals

S. S. Batsanov p. 267  abstract

Thermodynamic Functions for the Sorption of Aromatic Amino Acids
on KU-2 8 Sulfocationite in the H-Form

T. A. Krysanova, D. L. Kotova, V. F. Selemenev, and O. I. Rozhnova p. 271  abstract

Thermodynamic Characteristics of Beryllium Diiodide

S. A. Shlykov, A. V. Tutukin, and G. V. Girichev p. 274  abstract

Infrared Absorption Spectra of the Vapors of Methoxybenzoic and Nitrobenzoic Acid Isomers

Yu. Ya. Kharitonov and I. I. Oleinik p. 276  abstract

Adsorption of Alcohols from Binary Solutions on Activated Carbons

T. O. Ryabukhova, A. B. Arzamastseva, N. A. Okisheva, and S. N. Konovalova p. 281  abstract

Effect of Non-Nearest-Neighbor Interactions on the Properties of the {001}
and {011} Surfaces of Crystals with a Simple Cubic Lattice

I. V. Mamontov and Saif Mukhammed p. 284  abstract

On the Problem of the Determination of the Adsorption Phase Thickness
for the Adsorption of Solutions on Macroporous Adsorbents

A. M. Tolmachev, O. I. Trubnikov, and M. V. Borodulina p. 288  abstract

Theoretical Calculation of Limiting Equivalent Conductance for Multicharged Monatomic Ions
in Aqueous Solutions at 298.15 K

E. M. Kuznetsova p. 290  abstract


Proceedings of I All-Russian Conference on Quantum and Computational Chemistry
Held in Commemoration of V. A. Fock

Models and Methods of Quantum Chemistry

Hydrogen Atom in a Spherical Cavity: Degeneracy of Energy Levels and Boundary Conditions

A. V. Shcherbinin and V. I. Pupyshev p. 292  abstract

Interpretation and Calculation of the Parameters of the Model of Angular Overlap
of Orbitals Based on the Local Method of Effective Crystal Field

M. B. Darkhovskii and A. L. Chugreev p. 296  abstract

Relativistic Valence-Bond Method with Superposition of Configurations for Calculations
of the Electronic Structure of Diatomic Molecules with Heavy Atoms

I. I. Tupitsyn p. 304  abstract


Quantum Chemistry of Inorganic Compounds

Modeling of Small Clusters: A New Approach to Processes of Chemical Vapor Deposition

A. Yu. Timoshkin p. 312  abstract


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