Thermal Dissolution of Coals of the Metamorphism Series
in the Anthracene Fraction of Coking Tar: An Analysis of Correlations with the Chemical and Technological Properties of Coals
P. N. Kuznetsova,b,*, V. A. Safina,b,**, B. Avidc,***, L. I. Kuznetsovaa,*,
B. Purevsurenc,***, and Z. R. Ismagilovd,****
a Institute of Chemistry and Chemical Technology, Siberian Branch, Russian Academy of Sciences,
Krasnoyarsk, 660036 Russia
b Siberian Federal University, Krasnoyarsk, 660041 Russia
c Institute of Chemistry and Chemical Technology, Mongolian Academy of Sciences,
Ulan Bator, 13330 Mongolia
d Federal Research Center of Coal and Coal Chemistry, Siberian Branch, Russian Academy of Sciences,
Kemerovo, 650000 Russia
Correspondence to: *е-mail: kpn@icct.ru
Correspondence to: **е-mail: vsafin@sfu-kras.ru
Correspondence to: ***е-mail: avidmas@gmail.com
Correspondence to: ****е-mail: zinfer1@mail.ru
Received 12 August, 2020
Abstract—The thermal dissolution of coals of a wide metamorphism series from the deposits of Russia and Mongolia in the anthracene fraction of coking tar at 380°C was studied. According to the data of a correlation analysis, it was found that the reflectivity of vitrinite, the yield of volatile substances, the carbon content, and the temperature Tmax at which the main release of volatile substances occurs in the course of pyrolysis are the most reliable characteristic properties of coal to be used for the prediction of the conversion of its organic matter into quinoline-soluble substances. The dependence of the conversion on the above properties of coal has an extremum. The medium-rank coking coals with a vitrinite reflectance of 0.80–0.90, a vitrinite concentration of higher than 70%, a carbon content of 83–86%, a volatile matter yield of 35–39%, and a temperature of Tmax = 465–475°С had the highest rates of conversion.
Keywords: coal, thermal dissolution, conversion, correlation analysis
DOI: 10.3103/S0361521921020038