Influence of Activation Modes on the Specific Surface and Development of a Microporous Structure of Viscose-Based Carbon Fibers

V. A. Gorina* and E. G. Cheblakova**
Translated by N. Korovin

AO Research Institute of Graphite-Based Structural Materials NIIgraphit, Moscow, 111524 Russia

Correspondence to: *e-mail: valentgor@bk.ru
Correspondence to: **e-mail: elcheblakova@yandex.ru

Received 26 February, 2015

Abstract—The specific surface and porous structure of viscose-based carbon fibers produced by the Krasnoyarsk Plant of Chemical Fibers are investigated by low-temperature nitrogen adsorption using an ASAP 2020 device. The dependence of their specific surface and character of the pore-size distribution on gas-phase activation modes in the carbon dioxide stream at a temperature of 900°C is shown. It is established that the adsorption surface of carbon fibers can rise from 0.3 to 1900 m2/g during the activation. It is revealed that the prolongation of the activation time leads to an increase in the specific fiber surface owing to the appearance of numerous new micropores and the development of the microporous structure.

Keywords: carbon fibers, activation, specific surface, sorption capacity, porous structure, micropores

DOI: 10.3103/S1067821216070087