Mathematical Modeling of the Deoxidation Kinetics of Liquid Blister Copper with Carbon

V. P. Zhukov
Translated by N. Korovin

Ural Federal University, Yekaterinburg, 620002 Russia

Correspondence to: e-mail: zhukov.v.p@mail.ru

Received 30 September, 2014

Abstract—The mathematical description of various stages of the deoxidation kinetics of copper with charcoal is performed as applied to the reduction stage of fire refining of blister copper. It is shown that the process rate is controlled by the carbon mass transfer in the melt bulk and the reduction of oxygen contained in metal is performed according to the two-stage scheme. To intensify the copper deoxidation, it is recognized as reasonable to blow-in the finely dispersed coal immediately into the liquid metal bulk with inert or natural gas.

Keywords: carbon, deoxidation, mass transfer, time-dependent diffusion, anodic smelting

DOI: 10.3103/S1067821216060171