Study of the Mechanism and Regularities of Nitriding the Complex Ferrosilicoaluminum Ferroalloy in the SHS Mode

K. A. Bolgaru*, Lu. N. Chukhlomina**, and Yu. M. Maksimov***
Translated by N. Korovin

Tomsk Scientific Centre, Siberian Branch, Russian Academy of Sciences, Tomsk, 634021 Russia

Correspondence to: *e-mail: kbolgaru2008@yandex.ru
Correspondence to: **e-mail: liudnik@yandex.ru
Correspondence to: ***e-mail: combustion2005@yandex.ru

Received 19 May, 2016

Abstract—The results of an investigation into the mechanism of nitriding the ferrosilicoaluminum complex alloy under isothermal and nonisothermal conditions are presented. It is shown that the nitriding process of ferrosilicoaluminum is complex and multistage. It is established that, when nitriding the ferroalloy, the primary product is AlN; then Si3N4 is synthesized and Si3N4-based solid solutions are formed. The influence of the main parameters of self-propagating high-temperature synthesis on the velocity and degree of nitriding the ferrosilicoaluminum alloy is investigated. Critical parameters of the combustion process are revealed.

Keywords: nitriding, ferrosilicoaluminum, nitrides, self-propagating high-temperature synthesis

DOI: 10.3103/S1067821217050030