Features of the Use of Ammonium Nitrate in the Sulfide-Bearing Ore Mining
I. S. Karabanova, and E. V. Sivtsova, *
aSt. Petersburg State Institute of Technology (Technical University), St. Petersburg, 190013 Russia
email: *rheologyspb@gmail.com
Received 6 April, 2022
Abstract—
The modern idea of the mechanism and features of the thermal decomposition of NH4NO3 is described. The influence of additives of different nature on the thermal stability of NH4NO3 was analyzed. Various mechanisms of oxidation and subsequent dissolution of pyrite of sulfide-bearing ores in groundwater and its effect on NH4NO3, which is the main component of emulsion explosives, as well as the mechanism of autocatalytic decomposition of NH4NO3 in the presence of iron(II) salts, are shown. Methods for inhibiting the NH4NO3 decomposition are considered, which are designed to increase its stability during storage and under conditions of use in the sulfide-bearing ore mining.
Keywords:
ammonium nitrate,
thermal stability,
sulfide soil,
pyrite
DOI: 10.1134/S1070427222050032