Dissipative Processes in Filled Acrylate Polymers with Different Elasticities

T. R. Aslamazova*

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, 119071 Russia

Correspondence to: *е-mail: t.aslamazova@yandex.ru

Received 12 May, 2021

Abstract—Dissipative processes occurring in filled acrylate polymers in the temperature range from –150 to +150°С are studied in comparison with unfilled systems. It is shown that at positive temperatures dissipative α- and β-processes are characterized by a relaxation mechanism due to a rearrangement of links and segments in the presence of a filler. At negative temperatures, they are characterized by the phase mechanism of the μ‑process due to the formation of different forms of ice and a destruction of the polymer structure during freezing, which are most pronounced in the filled systems.

Keywords: dissipative processes, internal friction spectrum, polymer, elasticity, filler

DOI: 10.1134/S2070205121060046