Xianru Hea,b, Rui Zhanga, Kun Liuc, Shuwei Caia, and Guangsu Huangb
a College of Materials Science and Engineering, State Key Laboratory of Oil and Gas Reservior Geology and Exploitation,
Southwest Petroleum University, ChengDu, 610500 China
b College of Polymer Science and Engineering, Sichuan University, ChengDu, 610065 China
c Geological Research Institute of Shengli Oil Field, Sinopec. Ltd Corp., Dongying, 257015 China
e-mail: roryzhang1989@gmail.com
Received October 25, 2013;
Revised Manuscript Received February 10, 2014
AbstractSemi-diluted Xanthan solution has been widely used in various fields, especially in enhancing
oil recovery. The oscillatory shear and flow shear behaviors of Xanthan are important to oil flooding. The
oscillatory shear relates to molecular motions, while flow shear reflects flowing characterization. In oscilla-
tory shear mode, the storage modulus, loss modulus and tan
has been measured. Calculating relaxation
spectra through storage modulus, we found that the peak of segments relaxation heads to smaller relaxation
time side. Also, the quantity of relaxation units increases as concentration increases. However, the relaxation
time spectra are less affected by salinity. In flow shear mode, the relationship between shear rate and viscos-
ity has been investigated. As concentration or salinity increases, the pseudoplastic of Xanthan solutions
becomes more obvious. Furthermore, primary normal stress differences of Xanthan semi-diluted solutions
lightly increase at first then sharply decrease as shear rate increases. This abnormal phenomenon may refer
to wall slip.
DOI: 10.1134/S0965545X14050071
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