Relaxation Inhomogeneity of the Structure of Latex Polymers
Modified with Water-Soluble Phthalocyanine

T. R. Aslamazova, V. A. Lomovskoy, and A. Yu. Tsivadze

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences,
Leninskii pr. 31, Moscow, 119071 Russia

e-mail: sovet1@phyche.ac.ru

Received April 17, 2013;
Revised Manuscript Received February 13, 2014

Abstract—The possibility to quantitatively analyze change in the relaxation microinhomogeneity of latex
polymers during variation in the method of their preparation and modification with ionic phthalocyanine has
been shown. The probability of estimating the width of the continuous relaxation-time spectra via comparison
of the temperature dependences of the given internal-friction spectra and the temperature dependence of varia-
tion in the discrete relaxation time of the process has been demonstrated. The correlation between the tem-
perature–frequency variations of the polymeric relaxation modulus of the systems under the free-oscillation
regime and the degree of their relaxation microinhomogeneity has been considered.

DOI: 10.1134/S0965545X14050010

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