Electrical and Electrochemical Properties of Composites
on the Basis of Polyconjugated Polymers and Conducting Fillers
1

I. A. Chmutin*, G. I. Kozub**, A. T. Ponomarenko*2,
D. G. Belov**, and O. N. Efimov**

* Enikolopov Institute of Synthetic Polymeric Materials, Russian Academy of Sciences,
Profsoyuznaya ul. 70, Moscow, 117393 Russia

* Institute of Energy Problems of Chemical Physics (Chernogolovka Branch), Russian Academy of Sciences,
p/o Chernogolovka, Moscow oblast, 142432 Russia

Received December 30, 1999;
Revised Manuscript Received November 8, 2000

Abstract—New composite materials on the basis of polyaniline, polyacetylene, and graphite (a conducting
filler) were developed. Data obtained by electrophysical and electrochemical methods were examined. It was
established that the matrices of these composites were doped due to the ejection of charge carriers from the con-
ducting filler particles. Studying the electrophysical properties of the composites at various filler concentra-
tions, temperatures, electric field strengths, and other factors as well as their electrochemical properties, includ-
ing the doping with lithium cations, made it possible to establish the mechanism of the transport of charge car-
riers in such composite materials.


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