Effect of the Solvent Nature on the Structure
and Properties of Polyaniline

V. A. Vilenskii, I. B. Keivan, and V. I. Shtompel’

Institute of Macromolecular Chemistry, National Academy of Sciences of Ukraine,
Khar’kovskoe sh. 48, Kiev, 253160 Ukraine

Received January 14, 1998;
Revised Manuscript Received June 3, 1998

Abstract—The effect of the physical characteristics of a solvent on the structure and properties of polyaniline
obtained by chemically induced polymerization was studied. It is shown that use of the solvents having different
nature, polarity, and mechanism of interaction with polymer allows one to vary the macromolecular packing
density, degree of crystallinity, and conductivity of polyaniline.


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