Exploring Low Magnetization Induced Magnetocaloric Effect in Metallic Antiperovskite AsNCr3

Sarit Srimania, b, Shreyaskar Gangulya, b, Arnab Basua, b, Subarna Dattaa, b, and Soumyadipta Pala, b, *

aInstitute of Engineering and Management, Kolkata, 700091 India

bUniversity of Engineering and Management, Kolkata, 700160 India

email: *soumya.phys88@gmail.com

Received 17 July, 2025

Abstract— This manuscript explores the magnetocaloric properties of the antiperovskite compound AsNCr3, emphasizing its potential for sustainable refrigeration applications. Employing a combination of phenomenological modeling and density functional theory, the research reveals that the material’s low magnetization, arising from antiferromagnetic spin alignment, contributes to reduced hysteresis losses and enhanced thermal stability. Key findings include moderate entropy changes, a relatively narrow operational temperature span, and field-dependent phase transitions, indicating suitability for precise thermal management. The insights offer a pathway to designing efficient, environmentally friendly refrigeration systems based on low-magnetization materials.

Keywords: magneto-electric effect, phenomenological model, density functional theory, entropy change, heat capacity change

DOI: 10.1134/S1063783425602632