Methods and Approaches of the Sol–Gel Technology for the Surface Modification of Aluminum Oxide Powders
T. V. Khamova, O. A. Shilova*, and S. V. Khashkovskii
Translated by D. Marinin
Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences, St. Petersburg, 199034 Russia
Correspondence to: *e-mail: olgashilova@bk.ru
Received 7 July, 2017
Abstract—The results of studies, sol–gel synthesis, and the sedimentation stability of complex multicomponent sol–gel systems of the “silica sol modified with Co(NO3)2 · 6H2O, Al(NO3)3 · 9H2O with α-Al2O3 or γ-Al2O3 as highly dispersed filler” type are generalized. The physical–chemical processes accompanying the formation of modifying layers on the powder oxide particles are examined. The promising prospects of applying α-Al2O3 powders modified with a silicate layer of the composition (wt %) 1.2K2O · 3Al2O3 · 3.2CaO · 12.5Na2O · 28.1B2O3 · 52SiO2 in the fabrication of ceramic materials with improved strength characteristics are demonstrated.
Keywords: sol–gel method, powder surface modification, aluminum oxide
DOI: 10.1134/S1087659617060062