Diffusion of Sodium Ions and Electric Conductivity in Glassy
and Crystallized Na2O
Al2O3
2SiO2
Z. G. Tyurnina, N. G. Tyurnina, and S. I. Sviridov
Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences, nab. Makarova 2, St. Petersburg, 199034
Russia
e-mail: sviridov@isc.nw.ru
Received December 16, 2014
AbstractThe specific electric conductivity of glassy and crystallized samples of composition Na2O · Al2O3 · 2SiO2
has been determined. Diffusion coefficients of sodium ions have been determined by the sectioning method
with the measurement of the residual activity 22Na isotope. The parameters of the temperature dependence and
values of the diffusion correlation factor have been calculated. A significant difference of the diffusion mobility
of sodium ions in the glassy and crystallized samples has been found.
Keywords: diffusion, electric conductivity, glass
DOI: 10.1134/S1087659615060188
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