Synthesis and Characterization of Ceramics BaxMg(2 – x)F4 Activated by Tungsten

V. M. Lisitsyna, *, D. A. Musakhanovc, T. G. Korzhnevaa, A. V. Strelkovac, L. A. Lisitsynab, M. G. Golkovskyc, A. M. Zhunusbekovc, J. T. Karipbaevc, and A. L. Kozlovskyc

a National Research Tomsk Polytechnic University, Tomsk, Russia

b Tomsk State University of Architecture and Building, Tomsk, 634003 Russia

c Gumilev Eurasian National University, Nur-Sultan, 010008 Republic of Kazakhstan

Correspondence to: *e-mail: lisitsyn@tpu.ru

Received 28 April, 2022

Abstract—The possibility of radiation synthesis of luminescent ceramics from a mixture of Ba and Mg fluorides and WO3 oxide is shown for the first time. Synthesis is implemented in a powerful electron beam with an energy of 1.4 MeV by direct exposure of the charge to radiation. It is shown that the characteristic band is observed in the photoluminescence spectrum of the synthesized materials due to the introduction of tungsten, which indicates the incorporation of tungsten into the lattice during radiation synthesis without the use of additional substances in the charge.

Keywords: ceramics, metal fluorides, activator, radiation synthesis, structure, photoluminescence

DOI: 10.1134/S1087659623600199