Change of the Thermal Behavior of 55Bi2O3 45B2O3 Glass
at Annealing Close to the Vitrification Temperature

N. A. Babitskii, V. P. Zhereb, and T. V. Bermeshev

Siberian Federal University, pr. Svobodny 79, Krasnoyarsk, 660041 Russia

e-mail: irbis_btv@mail.ru

Received June 16, 2014

Abstract—The characteristic properties of relaxation processes for 55Bi2O3 45B2O3 glass were described.
The pattern of changes of the vitrification temperature (Tg) is found to be quasi-periodic; the value of the endot-
hermic effect near Tg () and the difference between the softening point and the vitrification temperature (Tm
Tg) were determined. The temperature-time parameters of the transition from quasi-periodic to the continuous
change of the properties were determined and an explanation of such behavior of the system was offered.

Keywords: 55Bi2O3 45B2O3 glass, thermal behaviour, Tg, relaxation

DOI: 10.1134/S1087659616020024


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