Thermodynamic Properties of Norbornane Hydrocarbons

G. N. Roganov, S. V. Petrova-Kuminskaya, and I. V. Garist

Institute of Technology, Mogilev, Belarus

Received April 9, 1996

Abstract—Thermodynamic parameters of norbornane, exo- and endo-2-methylnorbornanes, exo,exo-, trans-
and endo,endo-2,3-dimethylnorbornanes were calculated for the state of ideal gas over the temperature range
298.15–1000 K from the molecular and spectral data. The additive approach that takes into account the partic-
ipation of atoms in formation of a cyclic molecule was used to estimate the parameters of the calculation
scheme for evaluating the enthalpies of formation (liquid and gas) and vaporization of norbornane hydrocar-
bons. Experimental values of the enthalpies of formation and vaporization of norbornanes were correlated, rec-
ommended values selected, and predictions made.

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