Phase and Isotopic Equilibria in the Anisole frame0 BF3frame1BF3 System
at 0.1frame20.8 MPa

S. G. Katal’nikov and N. E. Sizov

Mendeleev University of Chemical Technology, Miusskaya pl. 9, Moscow, 129848 Russia

Received March 29, 1996

Abstract—The BF3 to anisole molar ratio was measured in the liquid phase for the anisol · BF3 complex com-
pound at 281–443 K and under BF3 pressures of 0.1–0.8 MPa. The separation coefficient for boron isotopes in
exchange between the anisole · BF3 complex and BF3 was measured at pressures of 0.1–0.5 MPa. The experi-
mental separation coefficients are compared with those calculated from the data on phase equilibria and litera-
ture isotopic equilibrium data.


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