A. V. Barbov, V. E. Nabilkov, and M. V. Ulitin
Ivanovo State Academy of Chemical Technology, Ivanovo, Russia
Received November 30, 1995
Abstract—The values of the hydrogen content in Raney nickel and in a porous nickel catalyst are found, and
the heats of hydrogenation of organic reagents both by gas-phase hydrogen and hydrogen adsorbed at the cat-
alyst surface are determined in aqueous solutions of sodium hydroxide and in dimethylformamide–water binary
solvents. By-side processes involving residual aluminum of Raney nickel are shown to influence significantly
the results of the determination of adsorbed hydrogen amounts and the heat effects of liquid-phase reactions on
skeleton catalysts.
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