Experimental Determination of the Silica Solubility
and of the frame0 Activity Ratio in Standard
and Desalinated Seawater

A. V. Savenko

Faculty of Geology, Moscow State University, Moscow, Russia

e-mail: Alla_Savenko@rambler.ru

Received May 18, 2012; in final form, November 1, 2013

Abstract—The solubility of amorphous silica was studied in mixtures of riverine and marine waters simulating
the water composition at the river–sea geochemical barrier. The value of the thermodynamical equilibrium con-
stant was determined for the reaction of silicon solubility as frame1 = (1.71 0.01) 10–3 at 22C. A near-linear
dependence was found for the activity ratio of the frame2 and the salinity with the increase of this ratio from
1.00 in the riverine to 1.15 in the standard seawater.

DOI: 10.1134/S0001437014020222


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