Kinetics of Concerted Processes Occurring
in the Coordination Sphere of Polynuclear Complexes

T. S. Dzhabiev

Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow oblast, 142432 Russia

Received March 3, 1999

Abstract—The formal kinetics of concerted processes that occur in the coordination sphere of polynuclear
complexes is considered. The kinetics of consumption of one-electron oxidants or reducing agents in many-
electron oxidation (reduction) reactions catalyzed by clusters mimics the kinetics of a polymolecular reaction
in specific cases. These reactions are analyzed for clusters with different numbers of nuclei, and a comparison
with the experimental data is made.

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