I. V. Zhil’tsova, I. S. Zaslonlko†, and Yu. K. Karasevich
Semenov Institute of Chemical Physics, Russian Academy of Sciences, Moscow, 177977 Russia
Received December 4, 2000
Abstract—The Monte Carlo simulations of the reversible isomerization is carried out. The rate constants for
the forward and reverse reaction of dichloroethylene cis–trans isomerization are determined for a broad range
of initial conditions. Its is shown that the mutual effect of two actively interacting reactions occurring with
energy exchange leads to a number of kinetic features of the process: characteristic changes in the rate constants
during the process and the dependence of the equilibrium values of rate constants on pressure. The physical
nature of these features associated with the disturbance of the function of distribution over vibrational energy
due to the reaction is discussed.
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