The Effect of Reaction Conditions on MoB Activation
in 1-Octene Epoxidation with tert-Butyl Hydroperoxide

M. V. Nykypanchuk^a, M. O. Chernii^b, and Z. M. Komarenskaya^a, *

^a Institute of Chemistry and Chemical Technologies, Lviv Polytechnic National University, Lviv, 79013 Ukraine

^b Lviv Medical Institute, Lviv, 79015 Ukraine

*e-mail: zkomaren@mail.ru

Received July 7, 2015

Abstract—The change in the surface composition of a MoB catalyst in the epoxidation of 1-octene with tert-
butyl hydroperoxide and the effects of the reactant concentrations and reaction products (tert-butanol and 1,2-
epoxyoctane) on this process have been studied.

Keywords: molybdenum boride, catalyst, activation, epoxidation, 1-octene, tert-butyl hydroperoxide

DOI: 10.1134/S0023158416030113

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