Kinetics of n-Propylmercaptan Oxidation by Cobalt(III)
Octahydroxyphthalocyanine in an Alkali Medium

T. M. Ziyadova^a, *, V. A. Burmistrov^{a, b}, V. E. Maizlish^a, and O. I. Koifman^{a, b}

^a Research Institute of Macroheterocyclic Compounds, Ivanovo State University of Chemistry and Technology,
Ivanovo, 153000 Russia

^b Krestov Institute of Solution Chemistry, Russian Academy of Sciences, Ivanovo, 153045 Russia

*e-mail: ziyadova_tm@mail.ru

Received April 27, 2015

Abstract—The specific features of the association of cobalt octahydroxyphthalocyanine in aqueous alkaline
solutions have been investigated by electron spectroscopy. The kinetic parameters of the oxidation of n-propy-
lmercaptan by the phthalocyanine complex of cobalt in the absence of oxygen have been determined. The asso-
ciation leads to a decrease in the activity of the complex and to changes in activation parameters.

Keywords: n-propylmercaptan, catalytic oxidation, cobalt octahydroxyphthalocyanine, kinetics

DOI: 10.1134/S0023158416030186

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