I. G. Tarkhanova, V. V. Smirnov, and T. N. Rostovshchikova
Department of Chemistry, Moscow State University, Moscow, 119899 Russia
Received July 20, 2000
Abstract—The interaction between CCl4 and olefins with different structures is studied in the presence of cop-
per complexes with P-, S-, and N-containing donor ligands. Kinetic and spectroscopic studies show that the
ability of olefins to be coordinated to copper complexes governs the rate, the product composition, and the reac-
tion mechanism. Depending on the olefin and the structure of the metal complex, either typical radical-chain
reactions or processes without free radicals are observed.
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