Palladium(II) Octaalkylporphyrinates:
Synthesis and Spectral Properties

N. V. Chizhova^a, O. V. Toldina^a, and N. Zh. Mamardashvili^b

^a Institute of Solution Chemistry, Russian Academy of Sciences, Akademicheskaya 1, Ivanovo, 153045 Russia

^b Ivanovo State University of Chemical Technology, pr. F. Engel’sa 7, Ivanovo, 153000 Russia

Received May 21, 2007

Abstract—Palladium 3,7,13,17-tetramethyl-2,8,12,18-tetrabutylporphyrinate (I) and its 5,15-diaza (II), diphe-
nyl (III), and di(4-bromophenyl) (IV) derivatives were synthesized by the complex formation reaction of pal-
ladium(II) chloride with corresponding tetrapyrrole ligands in dimethylformamide, and their spectral properties
were studied.

DOI: 10.1134/S003602360809009X

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