Synthesis and Investigation of the Heat Capacity of Sm2Sn2O7 in the 346–1050 K Range
L. A. Irtyugoa, L. T. Denisovaa, Yu. F. Karginb, V. V. Beletskiia, and V. M. DenisovaTranslated by D. Terpilovskaya
aInstitute of Nonferrous Metals and Materials Science, Siberian Federal University, Krasnoyarsk, Russia
bBaikov Institute of Metallurgy and Materials Science, Russian Academy of Sciences, Moscow, Russia
Correspondence to: e-mail: antluba@mail.ru
Received 31 August, 2015
Abstract—Optimal conditions for the synthesis of Sm2Sn2O7 with pyrochlore crystal structure by solid-phase reactions were determined. The effect of temperature (346–1050 K) on the molar heat capacity of samarium stannate was studied by differential scanning calorimetry. Thermodynamic properties of Sm2Sn2O7 in the temperature range under study were determined using the experimental data.
DOI: 10.1134/S0036023616060097