M. V. Chugunova, I. K. Garkushin, and G. E. Egortsev
Samara State Technical University, Molodogvardeiskaya ul. 244, Samara, 443100 Russia
Received December 29, 2009
Abstract—A quaternary reciprocal system of fluorides, chlorides, and bromides of lithium and potassium was
partitioned into simplexes by a geometric method and by a graph method. Phase transformations and chemical
reactions in the boundary ternary reciprocal systems were described. A conversion line was experimentally
studied, and information on crystallizing phases within the composition prism of the Li,K||F,Cl,Br system was
obtained and confirmed by X-ray powder diffraction data. An immiscibility region in the LiF–KCl–KBr stable
triangle was outlined.
DOI: 10.1134/S0036023611040085
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