Reaction between Uranyl Dihydroxylaminate and Benzaldehyde
A. G. Beirakhov, I. M. Orlova, E. G. Ilin, L. V. Goeva, A. V. Churakov,
G. G. Aleksandrov, M. D. Surazhskaya, and Yu. N. Mikhailov
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences,
Leninskii pr. 31, Moscow, 119991 Russia
e-mail: abbey@igic.ras.ru
Received June 23, 2014
AbstractReactions of coordinated ligands in uranyl hydroxylaminate complexes with benzaldehyde were
studied. Methods of the synthesis of uranyl complexes containing E and Z isomers of benzaldehydoxime were
developed. The structures of [UO2((E)-C7H6NO)2{(CH3)2SO}2] and [UO2((Z)-C7H6NO)2{(CH3)2SO}2] were
determined by X-ray diffraction.
DOI: 10.1134/S0036023614120043
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