Some Features of Phosphorylation of Aminomethylated 2,6-Dihydroxynaphthalene
P. V. Slitikova, *
aBauman Moscow State Technical University, Moscow, 105055 Russia
email: *pvs@bmstu.ru
Received 3 October, 2022
Abstract—
The reaction of mono- and bisaminomethylated 2,6-dihydroxynaphthalene with hexamethyl triamidophosphite was studied. The effect of the intramolecular hydrogen bond O–H···N on the phosphorylation process was revealed: by changing the reaction temperature, it is possible to selectively implement it.
Keywords:
2,6-dihydroxynaphthalene,
hexamethyl triamidophosphite,
phosphorylation,
Mannich aminomethylation,
intramolecular hydrogen bonding
DOI: 10.1134/S107036322212009X