Synthesis of a New Series of β-Chloro-β-phenylvinylphosphonic Acid Chloride Derivatives

A. V. Egorovaa, b, *, D. M. Egorova, N. O. Sonina, I. E. Kolesnikovc, D. V. Pankinc, A. A. Manshinad, and R. I. Baichurine

aSt. Petersburg State Institute of Technology (Technical University), St. Petersburg, 190013 Russia

bSt. Petersburg Federal Research Center of the Russian Academy of Sciences, Scientific Research Center for Ecological Safety of the Russian Academy of Sciences, St. Petersburg, 197110 Russia

cCenter for Optical and Laser Materials Research, St. Petersburg State University, St. Petersburg, 190034 Russia

dInstitute of Chemistry, St. Petersburg State University, St. Petersburg, 190034 Russia

eHerzen State Pedagogical University of Russia, St. Petersburg, 191186 Russia

email: *diekerze54@gmail.com

Received 18 September, 2022

Abstract— An effective approach to the selective synthesis of vinyl phosphonates was developed based on the reaction of 2-chloro-2-phenylethenylphosphonic acid dichloride with some alcohols.

Keywords: vinylphosphonates, phosphonates, phosphonic acid dichloride

DOI: 10.1134/S1070363222100322