V. Yu. Novichkov
Institute of Rare Element and Mineral Chemistry and Technology, Kol’skii Research Center, Russian Academy of Sciences,
ul. Fersmana 14, Apatity, Murmansk oblast, 184200 Russia
Received October 13, 1995
Abstract—The behavior of tin difluoride in the eutectic mixture (Cs–K–Na)Cl is studied by linear voltammetry
and chronopotentiometry at a temperature of 800 K. Both the discharge process Sn(II) + 2e 
Sn(0) and the
recharge reaction Sn(II) 
2e 
Sn(IV) are found to be complicated by side effects. These effects involve
redistribution of anions of the first coordination sphere under a diffusion–kinetic control of the electrochemical
stage proper.
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