On the Asymmetry of Thermodynamic Fluctuations
of the Electrode Potential

B. M. Grafovz

Frumkin Institute of Electrochemistry, Russian Academy of Sciences,
Leninskii pr. 31, Moscow, 119071 Russia

Received March 9, 2004

Abstract—The asymmetry of thermodynamic fluctuations of the equilibrium electrode potential and the asym-
metry of thermodynamic fluctuations of the electrical double layer charge is characterized quantitatively on the
basis of third-order noise spectra.

Key words: thermodynamic fluctuations, electrode potential, electrical double layer charge


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