Co-adsorption of Anions and Low-Adsorbing Cations
within the AlekseevPopovKolotyrkin Model

B. B. Damaskin and O. A. Baturina

Moscow State University, Vorob’evy gory, Moscow, 119899 Russia

Received December 17, 1998

Abstract—Co-adsorption of an anion and a low-adsorbing cation is analyzed within the Alekseev–Popov–
Kolotyrkin model supplemented by two virial isotherms (APK+2VI). In the case of a high attractive interaction
of specifically adsorbed anions and cations, the condition dE_q=0 /dlnc > RT/F is insufficient to confirm the
Esin–Markov effect. The drawback of APK+2VI is in the existence of a potential range where the system of
isotherms has no solution.

Pleiades Publishing home page | journal home page | top

If you have any problems with this server, contact webmaster.