Some Notes on the Impedance Method for Mechanistic Studies
of Electrode Reactions^1,2

J. H. Sluyters^z

Frederik Hendriklaan 27, 3708 VA Zeist, Netherlands

Received November 21, 2007; in final form, February 07, 2008

Abstract—Conditions for obtaining high precision impedance data on electrochemical metal/electrolyte inter-
faces are discussed and some results pertaining to several electrode reactions presented. The importance of the
dropping mercury electrode is stressed.

Key words: electrochemistry, impedance, electrode reaction, mechanism

DOI: 10.1134/S1023193509010042

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