The Method of Double Cathodic-Anodic Potential (Current)
Pulses for Synthesis of Composite Coatings Prussian Blue
Polypyrrole
on Optically Transparent Electrodes

N. V. Talagaeva^a,b, P. A. Pisareva^a,c, A. K. Grebenko^d,
M. A. Vorotyntsev^a,b,c, and E. V. Zolotukhina^a,b,z

^aInstitute of Problems of Chemical Physics, Russian Academy of Sciences,
pr. Akademika Semenova 1, Chernogolovka, Moskovskaya Oblast’, 142432 Russia

^bMendeleev University of Chemical Technology of Russia, Miusskaya pl. 9, Moscow, 125047 Russia

^cLomonosov Moscow State University, Vorob’evy Gory 1, bld. 51, Moscow, 119234 Russia

^dInstitute of Solid State Physics, Russian Academy of Sciences,
ul. Akademika Osip’yana 2, Chernogolovka, Moskovskaya Oblast’, 142432 Russia

Received December 22, 2014

Abstract—An original method of one-step electrochemical deposition of electroactive composite films from a
mixed solution of precursors of the organic and inorganic components in the mode of double cathodic–anodic
pulses is used for the formation of Prussian blue/polypyrrole films on the surface of optically transparent elec-
trodes. The deposition parameters are chosen (the order of deposition of components, the number and amplitude
of polarizing pulses, the pulse length) which allow the deposition of composite films with good adhesion to the
electrode surface and the high stability of the redox-transition Prussian blue/Prussian white.

Keywords: Prussian blue/polypyrrole composites, method of cathodic–anodic pulses, optically transparent elec-
trodes

DOI: 10.1134/S1023193516010110

Pleiades Publishing home page | journal home page | top

If you have any problems with this server, contact webmaster.