L. K. Sharma, S. Kumar, S. Singh, and R. K. P. Singhz
Electrochemical Laboratory of Green Synthesis, Department of Chemistry, University of Allahabad, Allahabad-211002, India
Received September 25, 2008
Abstract—The electroorganic synthesis of 5-substituted-2-amino-1,3,4-oxadiazoIes from semicarbazone and
5-substituted-2-amino (substituted amino)-1,3,4-oxadiazoles from acylhydrazines and isothiocyanates were
carried out at platinum electrode. This is an environmentally benign method in the field of electroorganic reac-
tions under controlled potential electrolysis at platinum electrode in an undivided cell. The use of a non-aqueous
solvent and supporting electrolyte facilitate cyclization on platinum electrode in this technique. The details of
this synthetic method are described in the text.
Key words: electrooxidation, controlled potential electrolysis, supporting electrolyte, oxadiazole, acylhydra-
zine, acylthiosemicarbazone, platinum electrode, green chemistry
DOI: 10.1134/S1023193510010040
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