Energy Characteristics of Chemical Bonds
and Radical Reorganizations

E. A. Miroshnichenko, Yu. D. Orlov, T. S. Kon’kova,
Yu. N. Matyushin, and Academician A. A. Berlin

Received July 8, 2015

Abstract—Based on relationships between the mean thermochemical bond energies (MTBEs), bond dissocia-
tion energies, and enthalpies of atomization, a method have been proposed for calculation of MTBEs and the
energies of reorganization of molecular fragments into radicals (radical reorganization energies) in the course
of a monomolecular radical decomposition reaction. The method makes it possible to calculate the radical reor-
ganization energies and MTBEs of organic and organometallic compounds, including polyradicals and aro-
matic compounds.

DOI: 10.1134/S0012501615110081

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