Magnetic Effects of Photochemically Induced Reactions
in Dispersions of Aromatic Ketones in Polyelectrolyte Complexes
of Polyacrylic Acid and Cationic Surfactants

V. B. Ivanov and V. V. Selikhov

Semenov Institute of Chemical Physics, Russian Academy of Sciences, ul. Kosygina 4, Moscow, 117977 Russia

Received July 5, 1996

Abstract—The increase in light scattering during photolysis of benzophenone dispersions in polyelectrolyte
complexes on the basis of polyacrylic acid and cetyltrimethylammonium bromide was found to be strongly
affected by a magnetic field. These effects are one or two orders of magnitude stronger than the primary mag-
netic effects, which are measured by the influence of the field on the accumulation of the products formed dur-
ing photochemical reduction of the ketone. Analysis of light scattering spectra and the dependence of the mag-
netic effect on the sample properties and irradiation conditions shows that a magnetic field accelerates structural
transitions in micron-sized particles, thus increasing their refractive index.


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