Assessing the Carcinogenicity of Carbon-Bearing Binders

O. F. Sidorova, *, A. A. Deryuginb, **, and A. Yu. Sidelnikovb, ***
Translated by Bernard Gilbert

aYeltsin Ural Federal University, Yekaterinburg, Russia

bAO Vostochnyi Nauchno-Issledovatel’skii Uglekhimicheskii Institut (VUKhIN), Yekaterinburg, Russia

Correspondence to: *e-mail: siderole@mail.ru
Correspondence to: **e-mail: deryugin.alexandr@yandex.ru
Correspondence to: ***e-mail: art-sidof@yandex.ru

Received 5 December, 2016

Abstract—Methods of determining the carcinogenicity of carbon-bearing binders in terms of their benzo[a]pyrene content and the benzo[a]pyrene emissions in binder carbonization at temperatures up to 850°C are considered. In the laboratory, CARBORES-T and CARBORES-P binders with reduced benzo[a]pyrene content are studied, as well as the industrial carbon pitch from which they are derived. It is found that predicting the carcinogenicity of carbon-bearing binders in terms of their benzo[a]pyrene content is unsatisfactory, largely because the formation and emission of benzo[a]pyrene on binder heating is ignored. Quantitative determination of the benzo[a]pyrene emission in the carbonization of the binders may be regarded as a more reliable and more universal method. It may be used to compare the carcinogenicity of products derived from coal and petroleum, as well as binders that do not contain benzo[a]pyrene.

Keywords: benzo[a]pyrene, carcinogenic polycyclic aromatic hydrocarbons, pitch, CARBORES binders, petroleum coke, visbreaker residue, coking additive, pitch coke, Bakelite powder, polyethylene, carbonization

DOI: 10.3103/S1068364X16120085